I've not used my current Samsung S4 Phone abroad. But, as GPS is global, it should be no different from the UK. You need the "Locate£ and the "Mobile Data" icons both switched on, on my S4, in order for the Ordnance Survey Apps to pick up your location. The Mobile data, I assume prefers a network to function, but when out of signal range the GPS still works, I just need to tell the phone, when prompted, to ignore the missing signal..
Your phone will automatically search for a network once abroad, if you let it. No idea what the charges would be abroad. But if you have pre loaded the maps before you travel, then there should be little data transfer required. Plus as I mentioned above the GPS still works when out of network signal range, but on my phone I still need to switch on "Mobile data" to get the OS Apps to work.
I find the OS Apps really good and tend to have my paper map as a back up and my little S4 as my primary navigation tool these days. I also have an external battery pack to recharge the phone on the fly, for longer walks.
Have a great trip.