I usually like to walk fairly uncluttered in terms clothing (no not that way!). In the warmer weather a trekking shirt and a pair of Craghoppers will do. If it gets a bit colder I swap to a wicking base layer, perhaps with a light weight fleece jumper if needed. Anyway to the nub - it has suddenly got a bit colder and blowier in this neck of the woods so the other day I added an outer fleece. Part of the way round I started to feel distinctly damp and the outside of my fleece was quite wet to the touch. The only possible cause, given the weather at the time, was moisture wicking through and condensing as it met the cold air.
Today we had a trip out on Exmoor and it was distinctly cold, overcast and quite windy so I wore my Paramo jacket for the first time in ages. By the time we were a quarter of the way round, I had the same clammy feeling, especially round the arms and shoulders, and water was literally dripping out of my cuffs. When we finished I had a good look at the jacket. The lining was damp, particularly over the shoulders. Again, it hadn't rained so condensation must be the cause.
I am not sure how to prevent this. A working body produces heat; nature uses sweat to cool us down by evaporation; warm damp air will condense when it meets a cold surface. A faster airflow might evaporate the condensation quicker but today we had a force 5 to 6 and it didn't help. If you did not wear enough to retain body heat then you would not sweat but hypothermia seems a bit drastic. It is finding that balance to feel comfortable without perspiring given the varying workloads and environmental conditions associated with hiking
What it does bring to mind though, is all the threads we have had on this forum about leaky jackets. As others have pointed out before, condensation could well be the cause in may cases and my experience suggests it is easily underestimated as a contributing factor.